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Axis 2 – Physics of multifunctional materials

     One of the research activities of the Axis 2 is centred on the growth, study and engineering of the fundamental properties of functional oxides of transition metals.
More specifically, we synthesize, combine and study ternary oxides in thin film form, such as perovskites ABO3 and garnets A3B5O12. These oxides have a multitude of remarkable and often coupled properties, such as magnetism, superconductivity, giant magnetoresistance, the metal-insulator transition, piezoelectricity, etc.
     One of the major current challenges of the research lies in the control and manipulation of the fundamental interactions governing the electronic properties of these oxides, in order to control the functionalities at room temperature.
     The originality of our team is related to our experimental developments (in film growth and in physical properties measurements) around the engineering of complex oxides allowing us to create "tailor-made" materials thanks to our long experience of pulsed laser deposition (PLD). In these materials, we induce and study  the functional properties of interest, such as for example the magnetoelectric coupling, the metal-insulator transition, magnetism and semiconductivity, the two-dimensional interface conductivity (2D electron system), etc.
     Our skills range from the synthesis of materials and their physicochemistry in thin films, to the studies of their physical properties, via specific instrumental developments. The latter are used to follow the growth of functional oxides in real time, and for the investigation of their magnetic, optic, magneto-optic and magneto-transport properties.

 

Physics of spin crossover materials

          The Axis 2 team is also conducting a fundamental physics study on Molecular Switching. The team also coordinates a CNRS Research Group on this subject at the interface of Physics and Chemistry. Molecular switching is a property of certain solids so-called "multistable" solids, presenting at the molecular level several possible states between which switching is possible, in a reversible way, under the effect of external factors that will be detailed later.

          The main purpose of molecular switching studies is the realisation of non-volatile optical memories, i.e. not requiring energy to maintain the bit of information in a given state. In principle, a bistable system can contain, at least temporarily, one bit of information. However, it seems necessary to gather a few hundred molecules in order to permanently store the information in point-to-point memories, whereas a slightly larger number would be needed for holographic memories. Whatever the type of memory chosen, the extreme smallness of the molecular dimensions should lead to memory densities much higher than current standards.